![]() ![]() Theformer tests mainly showed that the methodology was not suitable for this type of refractorymaterial due to the crucibles cracking during the experiments. The experimentsalso showed that T12 refractory in particular was very susceptible to abrasive wear after beingoxidized.The slag smelting experiments were carried out through two different methods, by melting slagin MgO-C crucibles and by melting pressed slag briquettes on top of refractory bricks. Further, the oxidation depth of each materialwas measured to 9-10 mm, 2-3 mm and 2-5 mm for the T05, T10 and T12. The experiments showed that themass loss during the pre-heating is greater for refractory with higher carbon content, withexception to T10, where the mass losses were measured to 3.76 – 4.01%, 1.06 – 1.28% and6.28 – 6.33% for T05, T10 and T12 respectively. The simulations also showed trends on how theliquid viscosity behaved with different slag compositions and how the solids content changedwith temperature.The oxidation experiments were performed on the different MgO-C refractory types, where thebricks with 10% carbon also contained Al2O3 antioxidants. ![]() A few different slagsfulfilled the CaO and MgO saturation limits proposed by Höganäs AB and could be consideredto test experimentally for further evaluation. The oxidation effect on the refractory material wasalso studied through pre-heating simulations in chamber furnaces, similar to the pre-heating ofa re-built ladle furnace.The thermodynamic calculations made in FactSage 7.0, using the FactPS and FToxid databases, resulted in a few different slag designs with different properties. Different CSAM slags weredesigned to meet certain process criteria such as MgO and CaO saturations and wereinvestigated through thermodynamic calculations using the FactSage software and throughlaboratory scaled slag smelting experiments. The present thesis work specifically investigated slag designed of the CaOSiO2-Al2O3-MgO (CSAM) system as well as the chemical and oxidative wear mechanisms ofthree different MgO-C based refractory materials from Höganäs AB, Halmstadverken, whichcontained 5, 10 and 12 wt% carbon (labeled T05, T10 and T12). Dueto the importance of minimizing material loss and to the environmental challenges to run asustainable industry, it is of interest to gain more knowledge of the behavior of the refractorymaterial in use. The wear could be divided into oxidative, chemical andabrasive categories, all behaving differently and all being influenced by different factors. MgO-C based refractory materials, often used in secondary steel making, are exposed to variouswear mechanisms in its application. 2019 (English) Independent thesis Advanced level (professional degree), 300 HE credits Student thesis Abstract ![]()
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